碳纤维性能优异,应用广泛,目前市场上的碳纤维主要是来源于石油和煤炭的聚丙烯腈基和沥青基碳纤维。近年来,随着石油和煤炭等不可再生资源的消耗,探索和发展生物质基碳纤维再次兴起,针对纤维素和木质素两种生物质基碳纤维前驱体原料,综述了粘胶基、Lyocell基、Ioncell基三种纤维素基碳纤维的研究现状,同时对木质素基碳纤维干喷湿纺碳化和熔融纺丝两种工艺做了简单介绍。最后,对生物质基碳纤维未来的研究重点和发展方向进行了展望。
Carbon fibers have excellent performance and are widely used,and that on the market re mainly made from polyacrylonitrile based and asphalt based carbon fibers derived from petroleum and coal.In recent years,with the consumption of non-renewable resources such as oil and coal,biomass based carbon fibers are rising again.Based on cellulose and lignin precursors,the research status of viscose,Lyocell and Ioncell based cellulose fibers were reviewed,and dry jet wet spinning and melt spinning processes of lignin based carbon fibers were introduced.Finally,the future research focus and development direction of biomass based carbon fiber were prospected.
[1] 崔峙,李姗,薛亚俊,等.浅析高模量碳纤维工业化及前景[J].化工新型材料,2019,47(11):33-35.
[2] Frank E,Steudle L M,Ingildeev D,et al.Carbon fibers:precursor systems,processing,structure,and properties[J].Angew Chem Int Ed Engl,2014,53(21):5262-5298.
[3] 贺福,赵建国,王润娥.粘胶基碳纤维[J].化工新型材料,1999(1):3-10.
[4] 张晓阳.粘胶基碳纤维及沥青基碳纤维技术进展及发展建议[J].化肥设计,2017,55(4):1-3.
[5] Dumanli A G,Windle A H.Carbon fibres from cellulosic precursors:a review[J].Journal of Materials Science,2012,47(10):4236-4250.
[6] Sporl J M,Beyer R,Abels F,et al.Cellulose-derived carbon fibers with improved carbon yield and mechanical properties[J].Macromolecular Materials and Engineering,2017,302(10):1700195.
[7] Wu Q L,Pan D.A new cellulose based carbon fiber from a lyocell precursor[J].Textile Research Journal,2002,72(5):405-410.
[8] Peng S J,Shao H L,Hu X C.Lyocell fibers as the precursor of carbon fibers[J].Journal of Applied Polymer Science,2003,90(7):1941-1947.
[9] Zhang L P,Sun W Z,Xu D,et al.Dope dyeing of lyocell fiber with NMMO-based carbon black dispersion[J].Carbohydrate Polymers,2017,174:32-38.
[10] Swatloski R P,Spear S K,Holbrey J D,et al.Dissolution of cellose with ionic liquids[J].Journal of the American Chemical Society,2002,124(18):4974-4975.
[11] Liu Y R,Nie Y,Lu X M,et al.Cascade utilization of lignocellulosic biomass to high-value products[J].Green Chemistry,2019,21(13):3499-3535.
[12] Spörl J M,Ota A,Son S,et al.Carbon fibers prepared from ionic liquid-derived cellulose precursors[J].Materials Today Communications,2016,7:1-10.
[13] Kuzmina O,Bhardwaj J,Vincent S R,et al.Superbase ionic liquids for effective cellulose processing from dissolution to carbonisation[J].Green Chemistry,2017,19(24):5949-5957.
[14] Lei L F,Lindbrathen A,Hillestad M,et al.Screening cellulose spinning parameters for fabrication of novel carbon hollow fiber membranes for gas separation[J].Industrial & Engineering Chemistry Research,2019,58(29):13330-13339.
[15] Liu Y R,Thomsen K,Nie Y,et al.Predictive screening of ionic liquids for dissolving cellulose and experimental verification[J].Green Chemistry,2016,18(23):6246-6254.
[16] Zhou L,Pan F,Liu Y,et al.Study on the regularity of cellulose degradation in ionic liquids[J].Journal of Molecular Liquids,2020,308:113153.
[17] 王均凤,聂毅,王斌琦,等.离子液体法再生纤维素纤维制造技术及发展趋势[J].化工学报,2019,70(10):3836-3846.
[18] Liu Y,Wang Y,Nie Y,et al.Preparation of MWCNTs-graphene-cellulose fiber with ionic liquids[J].ACS Sustainable Chemistry & Engineering,2019,7(24):20013-20021.
[19] 张锁江,周乐,聂毅,等.离子液体制备纤维素基碳纤维或碳膜的方法:中国,201910036373.7[P].2019-01-15.
[20] 曹其平,周景辉.木质素基碳纤维研究进展[J].中国造纸,2019,38(6):79-83.
[21] Choi D,Kil H S,Lee S.Fabrication of low-cost carbon fibers using economical precursors and advanced processing technologies[J].Carbon,2019,142:610-649.
[22] Bengtsson A,Bengtsson J,Sedin M,et al.Carbon fibers from lignin-cellulose precursors:effect of stabilization conditions[J].ACS Sustainable Chemistry & Engineering,2019,7(9):8440-8448.
[23] Byrne N,De Silva R,Ma Y,et al.Enhanced stabilization of cellulose-lignin hybrid filaments for carbon fiber production[J].Cellulose (Lond),2018,25(1):723-733.
[24] 徐保明,张弘,唐强,等.木质素基碳纤维制备方法的研究进展[J].化工新型材料,2018,46(4):23-26.
[25] 吴红,刘呈坤,阳智,等.木质素基碳纤维的制备及应用研究现状[J].高分子材料科学与工程,2020,36(2):176-183.
[26] Choi D,Kil H S,Lee S.Fabrication of low-cost carbon fibers using economical precursors and advanced processing technologies[J].Carbon,2019,142:610-649.
基金资助
国家自然科学基金(21776276);河北省重点研发计划项目(20324003D)
PDF
